Bis(acetonitrile)palladium dichloride
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| Names | |
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| Other names palladium dichloride bis(acetonitrile), bis(acetonitrile)dichloropalladium | |
| Identifiers | |
CAS Number |
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3D model (JSmol) |
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EC Number | 238-637-3 |
PubChem CID |
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| Properties | |
Chemical formula | C4H6Cl2N2Pd |
Molar mass | 259.43 g·mol−1 |
| Appearance | yellow-brown |
Melting point | 129–131 °C (264–268 °F; 402–404 K) |
| Hazards | |
GHS pictograms |   |
GHS signal word | Danger |
GHS hazard statements | H301, H311, H330 |
GHS precautionary statements | P260, P261, P264, P270, P271, P273, P280, P284, P301+310, P301+312, P302+352, P304+312, P304+340, P305+351+338, P310, P311, P312, P320, P321, P322, P330, P332+313, P337+313, P361, P362 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Bis(acetonitrile)palladium dichloride is the coordination complex with the formula PdCl2(NCCH3)2. It is the adduct of two acetonitrile ligands with palladium(II) chloride. It is a yellow-brown solid that is soluble in organic solvents. The compound is a reagent and a catalyst for reactions that require soluble Pd(II).[1] The compound is similar to bis(benzonitrile)palladium dichloride. It reacts with 1,5-cod to give dichloro(1,5‐cyclooctadiene)palladium.
References
^ Carretero, Juan Carlos; Arrayas, Ramon Gomez (2008). "Dichloro bis(acetonitrile) palladium". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn00908.CS1 maint: Uses authors parameter (link) .mw-parser-output cite.citation{font-style:inherit}.mw-parser-output q{quotes:"""""""'""'"}.mw-parser-output code.cs1-code{color:inherit;background:inherit;border:inherit;padding:inherit}.mw-parser-output .cs1-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .cs1-lock-limited a,.mw-parser-output .cs1-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/d/d6/Lock-gray-alt-2.svg/9px-Lock-gray-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .cs1-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Lock-red-alt-2.svg/9px-Lock-red-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration{color:#555}.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration span{border-bottom:1px dotted;cursor:help}.mw-parser-output .cs1-hidden-error{display:none;font-size:100%}.mw-parser-output .cs1-visible-error{font-size:100%}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration,.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-right{padding-right:0.2em}
